Chem. Phys. Lett. 380 (5-6), 774-779 [pdf]

 

Nanocomposite ta-C Films Prepared by the Filtered Vacuum Arc Process Using Ni Nano Dots on a Si Substrate

 

Churl Seung Lee, Tae-Young Kim, Kwang-Ryeol Lee, Jae-Pyoung Ahn and Ki Hyun Yoon
 

 

Recently, structural manipulation of tetrahedral amorphous carbon (ta-C) film at the nanometer scale has attracted much attention. We demonstrate a novel method to obtain a nanocomposite film where nanoscale columns of graphitic phase are embedded in a tetrahedral amorphous carbon matrix. When using a Si substrate with nanosized Ni dots on the surface, graphitic columns grew selectively on the Ni dots, while a dense ta-C film was deposited on the bare Si surface. The growth of the graphitic columns is closely related to the nanosized Ni dots that catalyze the graphitic carbon formation in a filtered vacuum arc deposition condition.